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Adsorbents for LPG contaminant removal

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rumirav

Petroleum
Dec 22, 2011
31
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Dear all,
Recently we have suffered some problems of Cupper Corrosion test failure in LPG. The LPG came from a caustic treatment for mercaptan sulphur removal. After caustic treatment, the LPG pass through a decanter (with NaOH/MEA solution) and sand filter, which are supposed to remove any caustic carryover from LPG. We do not see any caustic collected in the sand filter, however we have detected Na and nitrogen in LPG, so we suspect that it is not working properly. The sand filter seems not only not working, but also accumulating some contaminants: we have seen sometimes that LPG pass the cupper corrosion test in the inlet, but not in the outlet of the sand filter.
We are evaluating the possibility of substituting the sand by any other more effective adsorbent for caustic / nitrogen (amines). The possibilities are: activated carbon, Anthracite or alumina.
Has anyone experience with adsorbents for contaminant (caustic, amine, etc..) removal in LPG? Any idea / recommendation regarding the operation of the sand filter?
Thanks in advance
 
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