I agree with weldtek, depending on your material thickness and type of work, you could use a number of different fabrication techniques when it comes to welding process.
1. Is the welding single-sided open root welding?
2. Depending on the grade of DSS and process type, I use a different gas mix to ensure proper phase ballance.
a)2205- AR+1-2% AR or CO2 (depending on the base metals being joined, low grade 304 stainless w/Ar+2% CO2 may cause increased weld metal carbon content.
b)2507- I use GMAW-P with a 4-part gas mix AR+30He+1-2N²+1-2%CO2, and this gas mix gives excellent mechanical properties and toughness with very good phase balance.(I am required to use this gas mix by customer, I achieve good results GMAW-P with the above gas mix which costs less)
I currently utilize GMAW-P for welding DSS of grades 2205 and 2507 to them selves and to other higher Ni-Fe-Cr alloys. API technical manual 938-C gives information on welding duplex stainless steels and sample requirements for testing procedures. The welding consumables should be of the same composition currently used when using GTAW. A CV machine will need to be used, there are alot of machines to choose from. I currently use The Lincoln S500 powerwave with RapidX program wave forms.