Is this a double wall stack? Steam or hot water boiler? What operating temperature/pressure? 140 feet is a long run - you'll need to determine how much heat loss the stack gas will experience on its way up. If it's enough to reduce the temperature below about 55C, you'll have condensation. Worse case would be when the boiler is operating at low-fire, and the stack gas leaves the boiler at a lower temperature and volume.
I have experienced condensation problems with NG-fired hot water boilers (fire-tube type; 190F) that spend a lot of time at a low firing rate. The biggest concern is not the stack, but the boiler itself -- if that condensation can run down into the boiler, then you will have rusting of tubes, tubesheets, inner doors, etc.
If you determine that you have condensation, insulating the stack might be one answer. Another fix (although not the most energy efficient one) is to keep the stack gas hotter with a bypass damper inside the boiler. On a 4-pass boiler, the damper would direct some of the hotter second-pass gas into the fourth-pass outlet to raise the temperature of the gas leaving the boiler. An actuator modulates the damper according to stack temperature. No Green Building awards here, but it does work.
---KenRad