What sort of failures are you seeing with PVC? Are joints popping apart, or is piping failing in the middle, or at supports? This sounds like a cyclic service- is there the possibility of big "water-hammer" pressure spikes during switch-over? Is your piping indoor, or is it exposed to the elements? PVC does degrade rapidly in sunlight.
120 F is warm, but below the upper recommended service temperature for PVC which is ~ 140 F (60 C). But that's for piping without significant pressure- plastics de-rate in pressure capability very rapidly with increasing temperature, so you have to be careful. In your system, the combination of pressure and temperature may be beyond the recommended limits for PVC. Have a look at the IPEX website, Georg Fisher etc.- you may find you're beyond the limits they recommend. If you aren't, and the failures are in the piping rather than in the solvent joints at the fittings, you may have discovered something new and I'm sure the piping manufacturer (and all of us here) would like to know about it!
If pure pressure/temperature handling is the issue, CPVC will give you higher pressure/temperature service, but probably not enough if PVC is failing. Polypropylene will give you higher pressure/temperature service still, but without the ease of installation (i.e. you'll need to thermally weld the joints, not solvent weld them). PP-lined steel piping will be one step up from that in terms of pressure/temperature handling and pressure shock resistance. But if you go that route, make sure your piping is painted with a high quality coating so spills or other exposure doesn't rot it out from the outside inward.
Others here would be better at recommending a best choice for a wetted metallic material for this service (based on experience rather than compatibility charts), if that's the way you want to go.