I am bit surprised to see rather large difference in opinions, so I made a little check.
Google shows, at first glance, "dielectric union" used for home installations "to prevent galvanic corrosion".
And it is first time I see it, with over 15 years of work. Galvanic corrosion is allways mentioned, but more as urban legend, while in practice I simply see that mix all the time.
Not only that reference copper manual, like the one from Yorkshire company does not make any mention of it, but copper system manufacturers offer variety of copper-to-steel fittings, and even clearly declare that copper can be used in mixed installations without limits (except in cases I mentioned in previous post).
Canadian fitter's handbook I use in some international projects shows such fitting with direct fit of metal surfaces, without non-metalic seal.
Non-native use of english terms can make some trouble though it is adopted by manufacturers, and even official standards.
Dieletric isolation fitting in my (very wide) surrounding is exclusively used to isolate indoor metallic pipework from outdoor utility lines (gas or water or public hot water), to enable potential equalisation within buildings according to electrical codes.
In industrial and commercial buildings, electric continuation of every piece of pipework is mandatory for the same purpose (as potential equalisation is applied at limited number of spots), and each flange joint with non-conductive seal has to have additional bypass to ensure contact, which is apparently in direct contradiction with this "Googled" dielectric union...
Therefore, I could hardly call bad practice something what is every day practice for decades.