In concrete design to BS and SABS etc, we would not check for shear at 45 deg to the principal stress.
In this respect concrete design has been simplified (unlike soils design) and checking against the allowable compressive stresses is what is required.
If you watch a concrete sample failing in a compression testing machine, it actually fails in a combined tension/shear, but the corresponding compressive stress is what is measured and this is used as a basis for design.