dkm0038:
No, the latent heat of vaporization
DOES NOT equal the enthalpy of vaporization minus the enthalpy of saturated liquid. Your terminology is wrong and that’s probably what’s giving you the wrong idea and/or concept of what takes place inside the condenser and on a Mollier (P-H) diagram. There is no such thing as “enthalpy of vaporization”. Enthalpy is the property of a
substance and not of an action or process. Allow me to explain in detail in order to make sure we both agree on what is happening.
I assume that the steam condenses in the condenser at a constant pressure of 4.6 inches of Hg (gauge). Actually, this is not really true because there has to be a pressure drop within the condenser (otherwise, there would be no flow), but it is what is done in practice and this assumption yields a conservative answer. I also assume that the inlet steam is
SATURATED (as opposed to superheated). I’m also assuming that the formed condensate is also saturated (as opposed to supercooled). This means that you must evacuate the condensate as fast as it is formed. Under these conditions, the thermodynamic process is a horizontal line on the Mollier diagram that starts at the saturated vapor curve line on the right hand side of the diagram and extends horizontally to the left portion of the curve that represents the saturated liquid line. This horizontal line should be directly on top of the pressure value of 4.6 inches of Hg (gauge pressure – don’t forget to add atmospheric to convert it to absolute pressure) which can be read on the Ordinate axis of the Diagram.
Note that the horizontal line defines what is happening in the condenser: you are taking saturated steam and condensing it at constant pressure. The point at the saturated vapor curve defines the condenser inlet and its enthalpy can be read directly below, on the Abscissa axis. The point on the saturated liquid curve defines the product condensate and its enthalpy can also be read below, on the abscissa. The definition of the load on the condenser is the heat removed from the steam in order to convert it to condensate and this equates to the enthalpy of the vapor minus the enthalpy of the condensate – as represented by the length of the horizontal line. If you use the Mollier Diagram, you have the enthalpies of both streams. You can also use the NIST free database which you can find at:
Either way, you should find that the difference between the enthalpies is the 969.74 Btu/lb.
Additionally, I believe you either have a typo or someone made an error in the calculations’ results you were given. If you multiply the steam mass flow rate by the latent heat of vaporization you were given (& which I confirmed as correct), then you obtain
96,795,022 Btu/hr and
NOT 86,958,734 as the heat load you report. Somewhere, something is amiss and I recommend you check it out.
I hope this helps to bolster your confidence in the correct calculated load.