This thread seems to have gone all over the place.
You asked how to get the 100% Cv of a valve, knowing the Cv at 80%.
If that's all the information you have, you can only estimate.
MOST control valves have equal percentage characteristic. These vary, but 80% of TRAVEL with =% is about 45% of CAPACITY. So if you have (for example) a Cv of 20.7 at 80% of stroke, the full 100% travel Cv is 46. If it's linear characteristic, you can estimate pretty closely by multiplying the 80% Cv by 1.25. The characteristic also should be on the serial plate. Cv46P means that the Cv is 46, percentage.
You mentioned the Masoneilan software. I haven't used it recently but I did have a relationship with Masoneilan for 18 years, and their software, (and their sliderule), were all keyed to the 100% Cv which has always been posted in their literature. And if it's a Masoneilan valve, the serial number plate was stamped with the rated Cv, and the Characteristic. BTW: The numbers in the previous paragraph were from the Masoneilan 21000 series valve bulletin.
Psafety gives you an effective "Plan B" by calling the Manufacturer with the serial number and asking for a data sheet.
Many valve manufacturers engrave the part number of the plug in the flats at the top of the stem. If the serial number plate is gone, you might be able to read the plug part number, then check the parts supplement or the manufacturer's customer service rep, and get the Cv of the plug with that part number.