It is almost NOT possible to directly burn 100% biomass with the same pulverized fuel burning method in a large PC boiler and wish for continuous operation. Below are the major problems you are going to run into:
1. huge slaggings and foulings
2. quick corrosions and erosions
3. gas flow-induced vibrations and damages
4. fouling and poisoning of SCR
All these problems are because PC boiler design is not really suitable for biomass combustion (except for low ratio co-firing) because of high alkali metal and chlorine contents in the fuel and more flue gas generated from combustion. The only current good technology is for utility scale 100% biomass is fluidized bed, either CFB or BFB. Why fluidized bed is more suitable is because it has much lower combustion temperature thus has much lower chance for ash-melting and slag-building plus chlorine reacting with alkali metal to cause severe corrosions.
BFB is especially good for converting existing PC boilers. Rather than changing the bottom of the furnace into a grate type (also you don't see a grate type for a 200 MW class boiler), you change it into a bubbling fluidized bed. Fluidized bed makes fuel ignition and combustion much easier and more stable. There has been many examples of these conversions and tons of dedicated biomass-burning BFB boilers have been in good operations for many years.
For CFB, even though much better than BFB on boiler size and efficiency, it is not recommended for your application because:
1. too many modifications, you will almost have a new boiler
2. 100% biomass combustion does not generate enough ash for circulation needed for CFB operation
3. system is more complicated and harder on the operation and maintenance aspects, more investment, too
Another big reason why 100% biomass conversion is not possible is because of loosing of partial (almost 40%) steam output capacity. This is because biomass has much lower heating value and density. You can imagine burning charcoal balls vs. dry hay or tree branches in a camp fire or stove. If want to maintain the original MW by forcing to burn more biomass in a furnace, large volume of flue gas generated will make the gas (which carries fly ash) velocity too high and cause quick erosions of heating surfaces. To solve the problem you will have to reduce the spacings of tubes in the heating surfaces but this means also loosing steam production. The problem is definitely smaller for torrefied biomass like Davefitz suggests.
One more note, like many mentioned, make sure you have enough and stable biomass supply. I guess in this part the Europe is better than America both on the wood source and dedicated machinery availability sides but, still, I have to mention an example: a planned UK 300MW biomass CFB in the recent news has to ship fuel from all different countries in Europe plus US and South America. Your fuel yard also has to be about 10 times bigger than what you have right now. So please do not overlook the problems.