PVD coatings can help reduce corrosion, but primarily by serving as a barrier. If the coating has pinholes, or is scratched, the substrate will corrode, often faster than if they were uncoated due to galvanic effects. Pure aluminum, cadmium, and zinc, on the other hand, act as sacrificial coatings. They are more reactive than the substrate, but their oxides are stable and cling nicely to the base metal. They protect even when the surface is scratched or there are holes in the coating. In fact, the standard military test for these coatings is to inscribe an X in panels down to the base metal, then put them into a salt spray chamber. When corrosion (red rust if the substrate is steel) is observed on the exposed surface, the coating is said to have failed. With a chromate conversion coating, IVD aluminum coatings run thousands of hours before failure. Without the chromate conversion coating, they still hold out for hundreds of hours.
Jim Treglio
Molecular Metallurgy, Inc.