Your electricians are right to be wary around battery systems. Install HRC fuses as close to the battery as possible. Impose a total ban on the use of uninsulated tools on the battery itself, where the HRC fuse may not be able to provide protection against a direct inter-cell short circuit. If carrying out installation work on a large battery, leave a link out at the midpoint until all other connections are completed. This action effectively makes one high voltage battery into two lower voltage batteries until the final link is installed, reducing both the possibility of a severe shock and limiting the prospective fault current for the majority of the work.
Among the most dangerous DC systems are generator excitation systems for slipring machines, which can combine high voltages in excess of 1kV, current in excess of 4kA, and large inductance in the circuit. Switching these circuits usually employ a make-before-break contact to insert a dump resistor and perhaps a non-linear voltage dependent resistor into the field circuit to dissipate the stored energy prior to opeing the main field contacts and thus prevent a very intense high voltage arc being drawn.
Beware of all inductive circuits carrying DC: motor field windings can cause persistent arcs and very high voltages, even though they may only carry a few amps.
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