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Electroless silver plating thickness.

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smaher

Automotive
May 20, 2002
4
I currently have a problem with too much silver plating on a PCB. The Pb/Sn solder appears to be leaching the silver into solution and raising the liquidus point of solder. The result being poor infil of the solder joint.

I thought I understood that an immersion or electroless silver plating process was self limiting due to the substitution reaction which takes place between the copper of the board and the silver in solution. This limiting the plating thickness to approximately 0.15 microns as exposed copper is required for the plating process to work.
By microsection and SEM we have measured the plating on a "bad" board as being 2 microns.
On a "good" board the silver is barely visible.

Am I right in my thinking? Has anyone had a similar experience or could anyone explain why the plating is getting so thick?
 
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