Ex e refers to "increased safety due to a lack of arcs, sparks, or sufficiently hot surfaces". In some medium voltage machines ("medium" being anywhere from 1 to 10 kV), the air gap may be small enough that during specific transient events, a spark will develop between stator and rotor steel which could - in a Zone 1 environment - ignite a flammable gas mixture inside the machine enclosure. This does not occur with a lower (i.e. < 1 kV) rating because there is insufficient energy to cross the gap.
Note that both altitude (due to decreased gas density) and humidity - and the presence of conductive contaminants - may all affect the voltage level at which the phenomenon occurs.
As Kiribanda pointed out - there are a lot of machines out there operating in Zone 1 environments that utilize voltages up to 13.8 kV. Enclosures may differ from their low voltage relatives, and maybe different precautions in terms of preventing the ingress of combustible gas.
Converting energy to motion for more than half a century