Depending on the cost of gas (assuming your boilers will be gas fired) and the cost of electricity in your region, and how you produced your domestic hot water before the project, there may be some savings.
If you have an inefficient gas fired (or oil fired) hot water heater heater, you may save energy by using your condensing boilers to preheat domestic hot water, because your new boilers may have a better efficiency. That's if you don't have to keep an entire network of pipes hot during the summer just to preheat domestic water because you will use energy to keep those pipes on temperature and also the heat losses from the pipes may have to be cooled by your A/C if you have A/C in the building.
One efficient thing we do here is to install a high temperature heat pump to do simultaneaous cooling (for A/C and heat recovery) and heating. If you have a low temperature HWR (I'm assuming you have one because of the condensing boilers you are installing), you can reject the energy from the condenser of the high temperature heat pump to your hot water network. In winter and mid-season, that energy will heat your building and in summer, you can preheat domestic hot water and other things (reheat after deshumidification, preheat steam makeup, etc). Basically, we recover energy that otherwise would be lost in cooling towers, air evacuations and drain pipes to heat the building and domestic hot water . This is probabely out of reach for your boilers replacement project though.