Charge pump is not done for higher pressure. Max pressure is limited by the mechanical strnegh of gears, bearings, etc. of the larger pump and you can't exceed without problems. Charge is done to get the fluid into the inlet without cavitation. Or for holddown reasons of a hydrostatic piston pump. Charge requires an external relief valve set depending on the circuit, to 15 psi up to 400 psi.
You can't charge a larger pump with a smaller pump, in fact it would be worse than atmospheric inlet as the larger pump cannot pull enough fluid through the smaller one.
Some issues with using a pump as motor: The shaft seals are typically connected to inlet port on a pump, expecting no line pressure at all. On a motor, either a separate case drain is required, or a high ressure shaft seal with a shuttle valve to drain to the lower of two ports. If you are reversing this direction, or if you have two motors in series, or having any meter out load control, the downstream port may be toohigh for the shaft seals.
You didn not say if this dual pump is a two stage log splitter pump, or simply two independant gear sections in one housing. Dual pump sections can be used as you wish for size and pressure, but the two stage (kickdown) pump will give you fits. the large dispalcement section will shift in & out as pressure changes. Tow stage pump must alwasy push against a postive resistive load. Any motor or overrunning load will cavitate badly when the pressure rises enough to unload the large section. Motor is running at rate of say 20 gpm, when suddenly pump shifts down to 5 gpm. Motor cavitates and coasts, pressure drops, pump comes back onto 20 gpm, etc. Chatter, cavitation, line shock, etc can happen.
There is a limit to what we can help in patched together stuff without vendor data.
kcj