The meaning of kA (kilo-amp = 10^3 Amp) is the rating of the breaker obtained by standard procedures such as ANSI/IEEE C37-09 (Test Procedure), UL ( LV & MV), IEC –56, etc.
The prospective system short circuit must be less than the kA rating of the circuit breaker after considered derating or any unusual conditions.
Selection of circuit breaker should be based on in several electrical and other parameters such as continuous current, interrupting capacity, transient recovery voltage, capacitance current switching, etc.
Circuit Bkrs. manufactured after 1999 per ANSI standard to be used in metalclad swgrs. are not longer use MVA rating. Newest breaker rated for k=1 are certified with max. Interrupting rating for all operating voltage up to the max. rated voltage.
SUGGESTION: If you are in the ANSI marketplace check the standard such as IEEE Std 141 (Red Book), ANSI/IEEE C37.04, 06, 09, 010, 011 & 012.