Water generally weights 62.4pcf. So if your roof were a bowl (think parapets with a waterproof liner), a roof designed to ASCE 7 for typical roof live load could hold...0.321 feet of water...or 3.84 inches. Not much. It will depend on the shape of the tanks. If they're wide and short and bearing directly on the roof, it'll be spread out more. If they're tall and skinny, you could have an extremely high load. If they're somewhere between the two but sitting on a frame or some sort of grillage, you could be looking at some significant point loads.
In short - the 20psf live load is NOT for water tanks. A water tank is a unique applied load and should be treated carefully. Ask questions, find out what the actual load from the tanks are, and how many you'll have.