Basically, it has to do with thermal conductivity, which is the ability to transfer heat. The thermal conductivity for metals is greater in comparison to most non-metallic materials. Thus, during conditions where the metal and the plastic are exposed to the same cold medium, the metal will cool or transfer heat at a greater rate promoting the formation of frost on the surface. The plastic will have a thinner layer of frost. The total amount of frost for the metal and plastic will depend on the relative humidity of the gas medium. Remember, heat flows from high temperature to lower temperature until an equilibrium condition is reached. The rate of heat transfer for the material and relative humidity are key to frost build-up.