alvidz,
For a roof slab I would put it at the top to improve waterproofing. Otherwise the surface on which you want to control cracks the most, so if you have marble tiles on it, then the top, if you have exposed soffits, probably the bottom.
Unless it is greater than about 250-300 thick, then both faces.
tolchijb
Beam PT cannot be assumed to provide s&T reinforcement in the slab. Thise who suggest an elastic distribution of the prestress from a beam into the parallel slab don't know what they are talkking about so do not listen to them.