Nitrogen blanket pressure 4

[gd72]

Hello,

Can anyone tell me where I can find details of how to calculate or estimate the pressure of a nitrogen blanket. I can find examples of set pressures etc, but no detail as to how these were arrived at.
(We are using nitrogen on site for the first time to blanket a 30m3 Tetrahydrofuran storage tank. The nitrogen supplier is not being that helpful at present, just asking us to tell them what pressure we require.)

Thanks for your help.

 

[StoneCold]

gd72
The maxium pressure used is often determined by the tank design pressure which would be directly related to the relief set pressure. If you are wanting to know what the minium pressure is I am not sure there is an answer with out knowing more about your system.

You want to size the flowrate of the purge system so that it is large enough to back fill the tank when you are pumping out of the tank. If your tank is not rated for full vacuum you can suck in the tank if the nitrogen flow is too low.
You can also use the nitrogen blanket to pressurize the vessel and use that as the motive force to transfer liquid out of the tank. We do that sometimes.

We have also used the nitrogen blanket to add NPHSA to pumps when the requirement is not easily met with just the liquid static head. (High frictional losses in the suction piping were to blame)

I have wandered around a lot on this subject and I hope I have answered your question. If not at least I have given you a few things to think about.

Regards
StoneCold

 

[Montemayor]

gd72:

The correct Nitrogen blanketing pressure to employ in your application is related to the characteristics of your system. I assume you are applying it to a fixed, cone roof, API 650 or API 620 design. It depends on:

1) The MAWP and MAWV (Max. Allowable Working Pressure & Max. Allow. Working Vacuum) of your tank;
2) The liquid fluid stored;
3) The type of Nitrogen instrumentation, level controls, and relief devices employed;
4) The location and maximum site temperature expected;
5) Whether you vent the excess N2 to atmosphere or recompress.

For example, the vapor pressure of THF is approximately as follows:

Temp, oF VP, mmHg
100 275
110 375
115 400
120 425

Obviously, if you’re in Phoenix, Arizona you can expect your tank to exhibit about 450 – 500 mmHg pressure around mid-day. You want to select a Nitrogen pressure above the THF vapor pressure that will ensure that you have a positive pressure in excess of the THF vapor pressure such that the tank vapor space is pressurized above the atmospheric pressure. This keeps out air and water vapor and keeps the volatile and flammable THF contained under a positive, inert pressure.

Your tank’s vapor space pressure will swing in accordance with the level of fill, the temperature, and whether it is being filled or emptied of THF. As you lower the THF level, the vapor space volume increases and its pressure decreases. This is where the N2 supply valve would normally open, at a pre-determined set point. You want to avoid having a varying liquid level if possible, because this causes a demand for N2 when the level drops and an excess of N2 (that must be vented or recovered) when the level is subsequently raised (thereby increasing the N2 vapor space pressure). This creates a need for a liberal “dead-band” – that tank vapor space pressure range within whose limits the instrumentation is set to operate. Depending on the sensitivity and accuracy of your instruments, you may have to increase the limits of the dead-band. This is why you must take into consideration the tank’s pressure and vacuum limits.

You have a need to design for the lowest tank vapor space pressure (which activates the opening of the N2 supply) as well as the highest vapor space pressure (which activates the tanks vent relief system or conservation vent). The ideal storage tank allows you to impose a slight N2 vapor space pressure when it is practically empty (around, say 5-10” W.C.) and withstands the resulting pressure reached when the tank is filled with THF to the maximum height (approximately 90% of total capacity). But normally what takes place is that you have a specific design on your tank that you must adhere to and those limits are what you design the N2 blanketing system to operate within.

I have produced and stored THF in the past and I remember that I employed a dead-band of 20” W.C. in my storage tanks. Unfortunately, I don’t recall the pressure ratings on the tanks and the specific sizes.

I presume you will be employing API 650 or 620 tank(s) with cone roofs and the tank(s) will be anchored to a concrete ring foundation. I also assume you will monitor (& record) the vapor space pressure to ensure blanketing and also to reveal when you vent. Tight environmental emissions controls and N2 costs may require you to do this monitoring.

I hope this explains how to go about picking your blanketing pressure design criteria.


Art Montemayor
Spring, TX

 

[EGT01]

gd72,

The other's are giving good advice to help you determine your blanket pressure but it seems unclear whether you intend to tell your nitrogen supplier that is the pressure you need. I suspect it is the delivery pressure that your supplier is wanting to know and not just your blanket pressure you desire. In case you haven't thought about this, think about where the nitrogen is coming from and where it is going and whether it makes sense to have more than one pressure level of nitrogen in between.

For low pressure storage then your blanket pressure will also be low, so to minimize the diameter of your nitrogen distribution piping between supply and use point, you would be better off having a relatively higher nitrogen system pressure which you reduce at your point of use with your nitrogen blanket regulator.

Just for nitrogen blanket supply purposes, a pressure of 20 - 30 psig (or less) would probably suffice to your blanket regulator. If you want to use the nitrogen for other purposes, a nitrogen supply pressure of 60 - 100 psig may be desired. In any case, don't forget to consider what effect the supply pressure has on your storage tank relief rate in the event the blanket regulator fails.

Also, think about if there are any issues regarding the nitrogen pressure from your supplier. Is it a high pressure supply (say 400 psig) that will require a let-down station and adequate relief protection for the low pressure piping and equipment downstream of the station.

Here's a couple of links you may want to check for additional info about tank vents and blanketing systems.

http://www.grothcorp.com/products.htm

http://www.protectoseal.com/tankmenu.html

 

[25362]

Don't forget to use a reactivity inhibitor (aka stabilizer) such as BHT in dosages of at least 200 ppm (LYONDELL), especially for the "relatively high" temperatures mentioned by Montemayor.

 

[gd72]

Thank you all for your prompt and useful responses.
To answer a few point raised (and raise some more questions),
The tank in question is used to store spent THF used in a cleaning process and is horizontal cylinder type and has been loaned to us by the THF supplier. The supplier has not been able to provide detailed drawings for the tank but we have arranged for inspection and pressure testing to 1 barg.
The original thought was to control the nitrogen pressure in the tank between 0.35 barg and 0.38 barg using a regulated nitrogen supply and a pressure relief valve (relieved gases go to condensor)with emergency relief and vacuum in case of over pressure or nitrogen supply failure. (Nitrogen supply flowrate is 50% higher than maximum empty rate).
One further question raised: Do we have to maintain the blanket pressure above that of the vapour pressure of the THF, max THF vapour pressure should be 0.4 barg at 40 Deg.C (we are based in UK so 40 Deg.C is slightly optimistic !!.)
If possible we wanted to avoid going above 0.4 barg as we didn't want to class the vessel as a pressure vessel.

Once again thanks for your help so far and any more information would be greatly appreciated.

Thanks

 

[Homayun]

What you want to achieve is probabely to have a higher pressure in the vessel than the fluid vapor pressure to make sure that it does not vaporize. I don't exactly know what are the rules of thums for this, but I gather 1 bar above the fluid vapor pressure should be sufficient.

However, if you are using nitrogen to replace the liquid in the tank when liquid is being pumped out, that is a different subject and for that you should look at API 2000 where they describe venting requirements when moving liquids out or in a tank.

 

[jay165]

In addition to the excellent posts above, one other thing to consider is whether a sudden rain storm (after the sun has heated up the tank and contents) will cause rapid vapor condensation and thus have a greater N2 inflow demand than a maximum pump out case. Here in southeast Louisina, we frequently get such weather patterns in the summer. We bought N2 by pipeline and whenever there was a rain storm, the demand went way up (higher than pumpout). I didn't believe it until I saw the N2 meter readings.

 

[Montemayor]

gd72:

I address your latest question by stating that I believe that THF vapor pressure at 40 oC is 300 mmHg (absolute) and not 0.4 barG as you indicate. So your concerns for exceeding your 0.4 barG value should not present a problem. My source for THF vapor pressure data is found at:

http://www.s-ohe.com/tetrahydrofuran.html

Assuming that your tank employs torispherical heads, its dimensions should be approximately 2.838 m (8 ft) x 6.096 m (20 ft) – normally a nice, liberal size for such a tank. We don’t know the dead-band you inherit in such a tank with your application, but I would expect your instrumentation will not have any problems addressing the control needs. The logic and scope you have presented seem to be very much in line with what normally is expected in these type of applications. I wish you good luck.


Art Montemayor
Spring, TX

 

[gd72]

Once again, thank you for all of your responses. I have a much better understanding of what is required for my project. My apologies if some of my questions seemed basic but I needed to be sure that we were doing things correctly.

Thanks for all your help and advise.