Vic123,
Just to give you an idea of the differences:
Nett positive suction pressure required = Atmospheric pressure - vapor pressure - liquid friction pressure loss in pump - liquid accellerations in pump.
Density of liquid
Nett positive suction pressure required = gravity constant x density x NPSH. Here you see the large role of the density of the liquid. This is why NPSH is normally determined for water service, except when the liquid density is above that of water.
Vapor pressure
The vapor pressure of hydrocarbons is normally quite different from that of water and depends on the hydrocarbons used. Hydrocarbons will normally not have a specific (one component) vapor pressure, so correction could be difficult.
Viscosity
When the viscosity of the hydrocarbons is quite high, internal friction in the pump will lead to locations inside the pump where the vapor pressure of the liquid will be reached earlier, than will be the case with water.
Temperature and shear effects
With water the physical properties stay quite the same with differences in shear and the temperature effects due to heat input (friction and shear) in the pump are quite predictable. Hydrocarbons however can have significant changes in their physical properties, e.g. viscosity and vapor pressure, due to temperature en shear effects.