Try reading the foreword (I know not many do...) of 36.10. I think the original idea behind the schedule nos etc was to allow a standard schedule number to be used for a variety of pipe sizes for the same pressure rating. However...
"The original intent of the Committee was to establish a system of Schedule Numbers for pipe
size/wall thickness combinations which would have an approximately uniform relationship equal
to 1000 times the P/S expression contained in the modified Barlow formula for pipe wall thickness
as defined in the Appendix to this standard. The resulting Numbers departed so far from existing
wall thicknesses in common use that the original intent could not be accomplished. The Schedule
Numbers were then adopted strictly as a convenient designation system for use in ordering."
And for XS, XXs etc
"It was the hope in 1939 that the designation of pipe used commercially by all industry as
Standard weight, Extra-Strong, and Double Extra-Strong would gradually be replaced by Schedule
Number designation. However, owing to customs of over 50 years’ standing, demand and production
of pipe to these traditional dimensions is undiminished. Consequently, in response to a
demand from users, accepted practice for dimensions and weights of commercial wrought steel
and welded wrought iron pipe were added."
In some pipe sizes std and XS etc correlate to a schedule number and in some others they don't....
My motto: Learn something new every day
Also: There's usually a good reason why everyone does it that way