This perception that this expansion bottle will be empty is completely wrong. It would be full of fluid at the max normal operating pressure of the main line and hence this PSV 1002 will have to operate to relieve at that imposed backpressure.
Balanced bellows type PSVs' can tolerate some backpressure while conventional type PSVs' have a zero tolerance to backpressure at the exit. This is wrt the integrity in setpoint maintenance.
A balanced type PSV will, in this case, allow a max built up backpressure of up to 0.8x240psig = 190psig, with no setpoint drift, while a conventional type PSV is essentially a differential pressure relief device, and is completely useless in this application.
So, to allow for some room for increasing backpressure as PSV1002 operates, I would say you cannot have a main line operating pressure exceeding 150-160psig, and that PSV1002 should be balanced bellows type. The sizing of the RV should also take into account this max backpressure on this RV. This is a sloppy design, but given this is very small capacity solar thermal relief ( firecase relief is not applicable to piping, only to equipment designed to pressure vessel codes), it may be tolerated if these conditions can be met. You have a high pressure trip PAHH 1009 set at 150psig, so one of these preconditions appears to be met.