Okay, been doing a bit of websearching, for what it was worth.
All I can find is reference to cars where the whole car (top and bottom surface) slopes down to the center. And that is so the product can drain out better. Are you SURE that the bottoms of the cars you're seeing are straight?
I find this called a "funnel flow" design by the way, and not limited to pressurized cars.
Quote 1:
"The silhouette of some modern tank cars depart from the strictly barrel-like horizontal cylinder by the ends turning upward somewhat and the middle sagging slightly downward. This shape allows better drainage of the contents and may help to accommodate sloshing when in motion."
Quote 2:
"An interesting variant is the "Funnel Flow" tanker which is slightly sloped toward the middle from each end, giving it a bent appearance, but allowing it to be drained by gravity."
Note that these quotes are from people dealing with models, not from carmakers, so are not necessarily authoritative.