Reduce the emission from tank partial condenser vent 1

[tariq1900]

Hi,
I have cumene storage tank where I need to control tank pressure through pressure control also this system has a partial condenser to condense cumene vapor back to the tank. My concern is about the condenser vent, which is having a %LEL measuring device which it shows 100% LEL all the time. I need to dilute the cumene vapor by increasing the nitrogen blanket. Now the tank working pressure 0.035Kg/cm2 and tank level 45% and nitrogen blanket is 30 Nm3/hr. is that possible or not?

 

[bimr]

The relatively high vapor pressure of cumene suggests that this will not be possible and/or economical. Suggest you investigate the use of a vent condenser.

http://www.graham-mfg.com/usr/pdf/downloads/19.pdf

 

[Montemayor]

Your post doesn’t make logical sense. Either you are not communicating correctly or you are confused about the application of a nitrogen blanket on a storage tank.

For example, you state: “I need to dilute the cumene vapor by increasing the nitrogen blanket.” That means you already have an existing nitrogen blanket applied in the storage tank and you intend to increase THE NITROGEN VAPOR PRESSURE – or the total vapor space pressure in the tank. This also means that you must re-set the relief pressure on the conservation vent valve (or pressure relief valve) on the tank. You fail to state what the existing vapor space pressure is and what you propose to increase it to.

Regardless of what you increase the tank vapor space pressure to by increasing the set pressure on the nitrogen feed regulator, THERE IS NO CONSTANT VAPOR SPACE VAPOR FLOW OUT OF THE TANK. The tank “breathes” – it breathes “in” when the contents’ temperature is lowered or when the liquid level is lowered. When that happens, the nitrogen feed regulator admits more nitrogen blanket gas into the vapor space. This additional vapor space gas is not vented since the pressure relief valve is always set higher than the set pressure on the nitrogen feed regulator. (and both pressures SHOULD BE WELL BELOW THE MAWP OF THE TANK).

The tank also breathes “out” – when the level in the tank is increased due to pumping in liquid, or when the contents’ temperature is increased. When this happens, the vapor space pressure is increased and the conservation vent valve (or pressure relief valve) on the tank opens and relieves the built-up pressure in the vapor space. But ONLY THE EXCESS VAPOR PRESSURE IS VENTED, the relief valve seats back at the set pressure. It is only during this time duration that some vent vapor is lost to the atmosphere and during which time a vent condenser would be effective. The vent condenser would have to be installed down stream of the relief valve and any collected condensate would have to be collected and pumped back to the pressurized tank or collected elsewhere.

The above is what is “possible”. I don’t understand your question about what “is possible or not”.

 

[tariq1900]

Dear bimr & Montemayor
thank you for replaying to my post.

i want to clarify that the nitrogen blanket line is independent
of pressure control. its open all the time.

 

[ash9144]

"i want to clarify that the nitrogen blanket line is independent
of pressure control. its open all the time."

This is not possible.

I think maybe you need to start over with defining your problem correctly. Most of what you are giving doesn't make any sense.

 

[tariq1900]

please have a look to attached link which has a sketch for the Tank.

https://docs.google.com/present/edit?id=0AZmf1OPo93JUZGZ3cXQ2YmtfMTBjanc3NWZmZw

 

[Montemayor]

Tariq:

I don't want to have to sign up for Google's uploading/downloading service just to view what you are presenting. Why don't you use Eng-Tip's uploading through ENGINNEERING.com?

WHAT -exactly- are you doing? Are you purging your tank with a continuous flow of nitrogen (something I strongly doubt)? Or are you blanketing your cumene tank with a static volume of nitrogen gas at approximately 0.5 psig (or less)?

In order to contain your Cumene storage vapors, you must have a storage tank with an appropriate MAWP (Maximum Allowable Working Pressure). If you don't have that capability, you are applying the wrong tank design. What is the MAXIMUM Cumene vapor pressure possible in your storage tank (or maximum storage temperature)?

 

[bimr]

BAT's (Best Available Technology) in the chemical manufacturing industry for control of emissions from aromatic storage tanks includes closed venting to a vapor recovery unit, a burner, or a flare. It is no longer accepted practice to vent to the atmosphere.

Is the nitrogen system being used as a purge to maintain a Minimum Oxygen Concentration (MOC) for the flammable cumene?

The difference between a pad and purge; with the use of a nitrogen pad, you are preventing oxygen from entering the tank as it is at higher pressure. If you have a continuous purge, you just ensure that any oxygen that gets in is swept out.