On Carbon Steel vessel which requires Charpy Impacts per Code, what is governing thickness on Category D joint for your welding procedure? Your nozzle is 2" Sch. 80 and shell is 1.25" thick.
Your question doesn't conatin enough info. If the nozzle is not exempt from impact requirements you'd need a procedure qualified from .218" thru 1.25". Recall that cat D's don't require production impacts though.
The pipe is SA-333 Gr 6 which is exempt and shell is SA-516-70 Norm which is exempt. Category "D" is exempt from production impacts I agree. Should the procedure you are using be qualified for .218 (.1875-.375) or .75 (.75-1.5)range?