According to Ampacity for Aluminum and ACSR Overhead Electrical Conductors/1986 Second Edition of Aluminum Association Table 4-AMPACITY FOR BARE ACSR CONDUCTORS 325 A ampacity it is for 4/0 conductor [no sun and wind]. The ambient temperature 40oC and conductor temperature Tc=75oC.
If we consider formula from IEEE 242/ 2001 CHAPTER 9.5.2.3 Intermediate and long-time zones :
IE/IN%=SQRT(((TE-To)/(TN-To)-(Io/IN)^2*exp(-θ/K))/(1-EXP(-θ/K)*(230+TN)/(230+TE))*100
where:
IE is emergency operating current rating=500A,
IN is normal current rating=325A,
IO is operating current prior to emergency=325A,
TE is conductor emergency operating temperature 119,
TN is conductor normal operating temperature[75oC],
TO is ambient temperature,
K is a constant, dependent on cable size and installation type (see Table 9-5),
and considering the ACSR conductor as a small cable in air K=0.5 hrs. and θ=1 hr then the conductor reached TE=119oC if the load current was 325 A for long time period before and suddenly jumps to 500 A for an hour.