I assume from your posting that the area you washdown is outside and therefore exposed to the elements.
Usually where stormwater is separated there will be two distinct pipe networks, unless you happen to be particulary close to a river.
I would be wary about having a holding tank for your washwater. I would expect this will contain animal faeces (the reason the washwater needs to reach the sewer) and depending on the size and retention time of your tank this will give solids the chance to settle out in the tank.
Your statement about manually opening during a storm event is also a problem. I take it you dont have someone sitting around 24 hours a day waiting for it to rain?
To my way of thinking the simplest way to do it would be to have one network, used for both washwater and rainwater draining to a single point, a manhole say. In the manhole you have one entry and two exits. Each exit has a penstock (manual or hydraulic actuated), one connects to your sewer line the other to your storm water system.
So for day to day when no market is running and night time (default) the flow goes to stormwater. When your market is open and animals are defecating, followed by washdown the flow goes to sewer (you will obviously get some rainwater in the sewer if the market is open and raining, would that be a problem?). You could link the switch over between penstocks to something that happens when the market is being prepared for business (auctioneers lectern, lights, doors, etc) so this does the change automatically.
Alternatively, stick a roof over your market with downpipes.