In reference to evacuating a refrigeration system, since you're supposed to drain and discard the oil (and any water and contaminants) after an evacuation, I see no particular justification for synthetic oil.
If you're evacuating something that won't contaminate the oil, and I don't know what that might be, then the synthetic oil... is probably still not worth the money, because it doesn't get as hot in a vacuum pump as it would in an engine.
Mike Halloran
Pembroke Pines, FL, USA