There are many factors to contemplate when comparing heat transfer fluids, besides heat transport and heat transfer performance, which refer to safety, cost and operability, which would take up quite a long response to deal with.
1. Heat transport.
The volumetric flow rate
through the heater V (m
3/h), to transport a certain quantity of heat Q (kJ/h), is
V = (Q/[ρ]c)(1/[Δ]t)
where
[ρ] = density, kg/m
3
c = specific heat, kJ/kg K
[ρ]c = vol. sp. heat, kJ/m
3 K
[Δ]t, (out-in) temp. difference, K
High values of density and specific heat result in reduced flows and improved accompanying economies. Of course, a further reduction in flow rates can be achieved by increasing the [Δ]t; however, a temp. difference of 20-30
oC has proved to be advantageous in most field applications.
2. Heat transfer (HT)
Regarding just HT performance, let's say that besides thermal conductivity and specific heat, two other physical properties are of importance in determining the convective HT coefficient h, density and viscosity.
Simplified formulas can be used for comparison purposes, (e.g. the Sieder and Tate expression) for h, W/m
2 K, provided flow conditions in heat exchange equipment are in the range of 1 to 4 m/s.
One of them:
h = 0.0235 v0.8[κ]0.62([ρ]c)0.48d-0.2[μ]-0.32
where
[κ] = thermal conductivity, W/m K
[μ] = kinematic viscosity, m
2/s
d = internal tube dia., m
v = flow velocity, m/s
Assuming the ratio of bulk and wall viscosity to the 0.14 power is ~1.
As a ROT one can say that good h values can always be expected with low-viscosity HT fluids. Note the effect velocities have on h.
When comparing results (for about equal linear velocities) between synthetic heat transfer media and mineral-oil based fluids it has been found that both give almost equal results at ~300
oC, but differ at lower temperatures at which there is a small advantage for synthetic fluids; this difference becomes greater at lower temperatures.
3. General
It is worthy to note that the fluids' comparative influence on
heat transport and
heat transfer is well below the undesirable effects caused by deposits, decomposition and contamination of either, the heat-transfer medium or the consumer side.
Thus the decision on what high-temperature fluid to use shifts predominantly to
lower-temperature behaviour (including pumpability during start up in cold seasons) on the one hand and
thermal stability (ie, service life) considerations on the other.