The von mises stress has nothing to do with crack initiation. It is an indication of the onset of plastic flow. Go back to your strength of materials book and follow the derivation. It has to do with the observation that a hydrostatic compressive stress results in no failure. Such a stress is termed dilitational, that is, a stress that causes a change in volume. From this it was concluded that yielding must be due only to deviatoric stresses, that is, stresses that cause a change in shape. They (Huber, Henkey, and von Mises) took the total strain energy, subtracted the dilatational strain energy, and got the deviatoric strain energy. The math trail from that lead to the von Mises stress formula. But, concrete does not yield, so I think its safe to say that its deviatoric strain energy is zero, and that the von Mises stress is meaningless for concrete.
A stress is NOT a stress. Yes, all materials have a "stress" at which they fail, but different materials fail by widely different mechanisms, and so the measure of that mechanism is different. Do you really believe that concrete, mild steel, high density polyethyene and carbon fiber composite, for instance, all behave the same and can be analyzed in the same way? The con Mises stress is not a real stress. It is a stress convention. It is a quantity made up from real stresses that is used as a criteria for a specific type of failure. You might want to take a look at "Failure of Materials in Mechanical Design" by Collins. He deals with faiure criteria and how and when to apply them in chapter 6.
Rick Fischer
Principal Engineer
Argonne National Laboratory