Gas may or may not be saturated with water. It depends.
Is it always 100% relative humidity outside? No.
Yes, it is convenient to ASSuME this to progresss your calculations, because it is usually the worst case, i.e. conservative. Depending on what happens to the gas downstream, you may want to make this assumption, or you may want to find an analytical method that measures the water. It depends.
Good luck,
Latexman