My hardware store happens to also have plenty of 1 litre and 4-litre plastic containers of methanol on its shelves, since it is used as a thinner for shellac amongst other things. They also have acetone, PVC glue and primer (MEK and THF), lacquer thinner (various aromatic and oxygenated solvents) and numerous other HIGHLY flammable materials- and all the same in spray cans as well.
Storage safety isn't just about mitigating ignition sources. That's the focus of the electrical codes because ignition is the only part of the triangle they have anything to do with.
If this is a filling or dispensing operation, that's a very different story!
If this is simply storage, a flame-resistant cabinet bonded and vented in accordance with the manufacturers' instructions will provide sufficient protection in most jurisdictions. That also presumes typical low-firespread construction (i.e. this is not an old wooden buildng), and the normal protections against fire are also in place (sprinklers, smoke/fire detection and alarming etc.). Div 2 electrical area classification for these circumstances would be equivalent to swatting a fly with a sledgehammer.