Assuming you've used Mechanica's shell idealization, and that your column is a tall plate, the bottom edge of the plate should be constrained in all translation dof and 2 rotation dof. Rotation about the edge should be free. The top edge should be constrained in 2 dof (translation allowed in the compression direction) and 2 rotation dof (rotation allowed about the edge). I've asssumed that the load is compressive on the top edge of the plate.
If you're using solids, I think you'll need to create a line on the top surface and the bottom surface, and apply the above constraints to these lines. Otherwise you can't get a hinged condition - if you constrain the 3 trans dof on the bottom surface, you have also constrained all 3 rotation dof.
Also, you can go to the knowledge base on the ptc website, search under 1. suggested technique, 2. mechanica, 3. buckling, there will be a document titled "suggested technique for buckling analysis" -- tutorial for doing buckling analysis on a coke can.
Hope this helps...