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Amine Reboiler Tubes Running Dry

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Motrack

Chemical
Sep 27, 2017
7
Hi folks,

We have an amine reboiler that has experienced tube leaks in the "top layer" of the reboiler tube bundle. It appears that the tubes are running dry or that the CO2 is accumulating in the top of the reboiler. We plugged the leaked tubes, and guess what, the tubes right below the plugged layer started to leak. I've had some recommendations presented by different vendors - Figure (2) modify shell and add an extra vapor pipe that will have a 24" vapor liquid disengagement space (allowing the liquids to "slip" back down into the reboiler) and the vapors to escape to the Still. Seems plausible, but it is rather pricey. Figure 3 - modify control scheme to receive flow and liquid inputs to a valve that is on the downstream side of the reboiler, causing the reboiler capacity to decrease (or HO supply temp to increase). Can also increase the common outlet header to Still to a 24" instead of the existing 18". Figure 1 is the existing configuration. Another option presented is based on the material analysis of the leaked tubes, a replacement of the tube bundle with hastelloy material of construction. The material analysis cited deep external surface metal loss within localized areas due to acid corrosion from exposure to carbonic acid.

Schematics_rpqnhz.jpg

IMG_1861_soy3dc.jpg

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Curious if you have experienced this issue and how you corrected it.

Thanks.
 
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Sketches are very small but just about discernible. Proposed schemes seem to indicate severe foaming issues in the column, kettle vapor return line, within the kettle reboiler and not related to corrosion in the kettle tube bundle. Have you tried defoamers?

What materials do you have right now for the kettle tubes? If it is only carbonic acid corrosion, standard 22Cr duplex SS should do I think, without having to go for much more expensive Hastelloy. However, if there is high chloride content in the solvent, a solvent reclaimer or electro dialysis unit may be required.

 
They do not seem to have foaming issues.

Currently, we have carbon steel SA-179 tubes. The analysis for the leaked tubes suggested chloride content.
 
Sketches 2 and 3 are indicative of either insufficient vapor liquid disengagement headroom in the kettle reboiler or foaming. Increasing the backpressure on the kettle in sketch 3 isn't a good idea if you ask me - at increased backpressure on the kettle, high thermal duty can then only be maintained with more hot oil feed, which will in turn, increase tubeskin OD temperatures leading to thermal degradation of solvent.

Dont see why you need to use Hastelloy here if you can manage to keep Cl- content within limits.


 
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