PEFLWI,
Being in an industry that uses lots of trussed towers and catwalks, a bit of advice: If the tower is all by itself, with no bridges/catwalks running to it, the diagonal wind will control. Don't forget to bump up your wind load for the diagonal by the factor specified in note 4 of Figure 29.5-3.
If you've got a bridge/catwalk running to it, the wind blowing perpendicular to that should control your design - I never check the diagonal wind in that condition.
EDIT:
And there I go again, skimming through the important info in the first sentence. *sigh*
The best deep dive on wind loading (including diagonal) on pipe rack trusses is probably "Wind Loads for Petrochemical and Other Industrial Facilities" by the ASCE. It's a great reference to have. It even includes worked example problems.