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High Temp Sulfuric resistant materials

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twalicia

Chemical
Joined
Jun 16, 2003
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I am looking for a material suitable for use to make an agitator in a pressure vessel operating at 4 bar, max 150oC, submerged in boiling H2SO4 at 20% concentration. The vessel contain abrasive clay slurry at 30% solids con. Would appreciate some recommendation on a suitable material. Currently we use a lead lined agitator but are trying to phase out the lead in our product.

Thanks for the input.



 
Due to the abrasive slurry, cannot recommend any coated material.

Metals Handbook, 9th. Edn., Vol. 13, Corrosion, pp. 1152-1153, and the corrosion resistance chart from Astro-Cosmos both indicate that you can safely use zirconium or tantalum
(unalloyed) at the sulfuric acid boiling point.
 
Hacksaw, we don't use a pump. As the vessel is pressurised, we relieve the pressure from 4 bar to about 1.5 - 2 bar, then the slurry is sort of push through into a holding tank where we quench it to lower temp.

However, there is a hast-C valve at the bottom of the vessel.
 
sounds like a laterite ore digester; that's pretty rough service

if the valve is holding up, then you have a starting point for your materials selection, but you may need some hardfacing. Hast.C(C-276) valves are generally cast and are a slightly different from the plate and bar stock you'd be using to fabricate an agitator.



 
There are a number of coatings you can put on the agitator. Epoxy-based (or vinyl-ester) with silica sand filler might work for both corrosion and erosion.[atom]
 
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