Yes, NFPA 99 is the guideline for generators and elec systems for hospitals. Also, NEC article 517, NFPA 110 and (to a lesser extent) NFPA 101 (Life safety code).
But, none of these dictate exactly how you have to size it. For example, NFPA 99, 2005 ed, chapter 4 (elec systems), 4.4.1.1.9...