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6.6kV Submarine cable junction box explosion

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krisys

Electrical
May 12, 2007
458
The system:
This is at one of the oil producing offshore Well Head Towers (WHT). The electrical power to this WHT is supplied through 6.6kV submarine cable. The cable is terminated in an Ex 'e' junction box installed above the boat landing level. The system is energized about an year ago.
This is an unmanned tower. The junction box has hinged door, bolted while fully closed.

Incident:
Recently, during the visit to the WHT the junction box door was found ruptured and left hanging on the junction box (JB). However there is no charred marks inside the JB. The connections are found intact.

The 6.6kV connection is not covered with insulation boot. Now there is an argument that there could be some ionization inside the box due to the exposed 6.6kV terminal thus releasing the hydrogen. The accumulated hydrogen must have resulted in an explosion, thus rupturing the JB door.

There is another school of thought which argues that there could be some chemical reaction inside the cable insulation thus generating the hydrogen and which must have reached and accumulated in the JB cavity.

Now the question:
Does anyone has such experience of hydrogen gas generation and accumulation in the cavities in the oil producing towers?

If you can share your experience, it would be very helpful to me.
 
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Maybe an associated experience from the 1990's might lead you to an explanation.

The web page here
Link
discusses the problem of hydrogen permeation through the diaphragm of industrial pressure transmitters.

Part ways down the page, it discusses hydrogen generation from galvanic action:

"Hydrogen permeation can be caused by galvanic energy. Galvanic energy is an electrolytic reaction between two dissimilar metals. For example, processes with sea water (a weak electrolyte) and zinc-plated impulse piping will generate galvanic energy through corrosion. This galvanic energy breaks the bonds of the molecules containing hydrogen (in this example, water), yielding hydrogen ions.
H2O → H+ + OH− "

I saw this effect when galvanized pipe was connected to the transmitter's carbon steel process heads (which had some corrosion coating) on non-brine but midwest USA hard (magnesium/calcium) water lines.

If there's galvanizing zinc in the Ex JB, and brine leaked in, maybe there's potential for hydrogen generation via galvanic action.
 
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