Because if you review ASME/ASTM SA/A 240 material specification, the 410S maximum carbon content is 0.08% by mass, the 410 range is 0.08% to 0.15% by mass. However, ASME B&PV Code, identifies the 410S as ferritic, based on a P-No 7 grouping designation, whereas, 410 is a martensitic grade and is under P-No 6 grouping.