The 850 mV criterion is applicable to coated ferrous structures. It would be inappropriate to use it, for example, on bare steel or iron pipe, where complete polarization is unlikely and it would be an overly conservative criterion. IR drops in the soil must be considered when measuring the data, and this is probably its biggest weakness. Also, it is not valid when connected to metals that are more anodic (Al or ZN), but can be used when connected to copper.