I agree with Ron, but I would not seal the brick until you know that the efflorescence has stopped. Even with the soluble salts in the bricks or mortar, efflorescence will not occur, or will be very minor, if water is not migrating in the wall. I would first clean the efflorescence through scrubbing. If it it too stubborn to be cleaned this way, wet the wall, clean with a solution of 1 part muriatic acid to 12 parts water, and rinse the wall thoroughly when done.
Next perform the tests Ron recommends and replace damaged/soft/spalled bricks and remove all deteriorated mortar to the depth of sound mortar below, but to a minimum depth of 1/4". Proper tuckpointing procedures really help it last in the long run and increase its weathertightness; don't do it halfway.
I would then leave the brick for at least a year before sealing it with the siloxane. It needs to dry out thoroughly, and you need to confirm that the efflorescnce mechanism (water migration bringing the salts to the wall surface) has been broken. Then I would apply the siloxane.
The wait, to me, is key. If water is still getting in, the siloxane will prevent the salts from migrating to the surface. They can then build-up, exert pressure, and cause the bricks to spall.