In the top menu bar, under the choice for "Reports", the last two choices for "Print/View Design Data" and "Print/View Simulation Data" give you options to review loads hour-by-hour. I typically do not review this detailed data. I print system and zone reports under "Print/View Design Data", which automatically selects the time of peak coil loads. In you choose to model a plant, I believe there are similar choices, but haven't been there for a while.
In the "Systems" menu, tab for "Sizing Data", highlight "Zone Sizing", there are various choices in two drop-down menus on the right with which you should become familiar.
In the "Weather" menu, on the first tab you may change any of this information to suit local conditions and the program will generate new annual temperature profiles. We have a local ASHRAE chapter that provided detailed data for many locations in our state - data not found in the ASHRAE book series. Not sure where you can find published data for your local conditions. I have used long-term weather data from local TV stations for other places. The US military also offers weather data obtained from many of their bases worldwide. Don't have the title on hand, NAVFAC something. Bottom line ... if you trust the design parameters you input, I have found no reason to disbelieve the results.
You receive one attaboy (gender-free) for wanting to learn how software works before using the results.
The Commissioning Agent should ultimately rely upon trend log data to indirectly confirm proper water flow rates by reviewing leaving air and room temperatures and set points during appropriate seasons. The TAB Agent has a few options for their work, which you are free to specify. You could request measurements of all units during several times of the day. They could simulate diversity by partially closing isolation or control valves in non-peak zones. DDC is handy for this. Of course, the TAB report must document such things. I typically use automatic (spring-loaded type) flow control valves in systems with many small coils. These valves require nothing more than a quick pressure drop measurement for balancing. From one or two such measurements of all units at different times, one can usually surmise if sufficent pressure would be available at different load conditions. But only time will tell. NEEB or AABC standards must address this as well. I'll check and relay anything interesting.