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Economic dealing with H2S separated from Amine Unit

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arahmans

Chemical
Feb 10, 2014
3
Hi,
Any one has former experience to advice;
Which will be more economic, converting H2S to elemental sulfur or to Sulfuric acid?
Thanks,,
 
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Do you have access to an acid plant?
What is the relative value in your local of S and H2SO4?
What is the required energy input for the two options?

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P.E. Metallurgy, Plymouth Tube
 
Dear EdStainless,
Thank you for your response,
I have not access to an acid plant.
S price = H2SO4 price * 2.59
I do not energy inputs.

If available, what is the relative capex & Opex of SRU to Sulfuric acid plant in the case of the same H2S feed to both plants?
For the current case , Acid Gas Stream as following:
Unit Acid Gas Stream
Vapour Fraction 1
Temperature C 50
Pressure psig 5
Molar Flow,kgmole/h 71.4113788
Mass Flow,tonne/d 62.22920921
Liquid Volume Flow,m3/h 3.87925353
Composition
Mole Frac (CO2) 0.158110893
Mole Frac (H2S) 0.797398247
Mole Frac (Methane) 0.000479617
Mole Frac (Ethane) 0.00030907
Mole Frac (Propane) 0.000206551
Mole Frac (i-Butane) 1.14E-05
Mole Frac (n-Butane) 4.88E-05
Mole Frac (i-Pentane) 0.005704713
Mole Frac (n-Pentane) 0.005464379
Mole Frac (n-Hexane) 0.005208501
Mole Frac (Mcyclopentan) 9.91E-06
Mole Frac (n-Heptane) 0.003617801
Mole Frac (n-Octane) 0.000777642
Mole Frac (n-Nonane) 0.000246288
Mole Frac (n-Decane) 1.71E-05
Mole Frac (H2O) 0.022389078
Mole Frac (MDEAmine) 7.62E-25

Thanks & Best Regards,,
 
I would start by contacting the companies that build this equipment. There are a handful world wide that design and build acid plants, likewise there are ones building pure S facilities.

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P.E. Metallurgy, Plymouth Tube
 
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