I have no idea where you came up with your expansion tank ideas, but I've always designed based on the following.
The expansion tank is added either to the air separator between the vent and separator, or between the air separator and the circulating pump(s), the point of neutralized pressure.
Now, the pumps go in the system before the chillers, and after the boilers - upstream from chillers, and downstream from boilers.
This logic would dictate that the expansion tank would be installed downstream from the boilers, and upstream from the chillers.
ASHRAE sells a book titled, "HVAC: Equations, Data, and Rules Of Thumb" by Arthur A. Bell, Jr. It's a very handy book, and the section on Chillers has some piping schematics and they show the expansion tanks upstream of the chiller.
If I'm wrong, let me know. I would like to design properly, but I've designed based on the stated reasons.