myname_earl
Chemical
- Aug 31, 2022
- 51
Background: Two 30-year-old, 20", 304L, triple offset, butterfly valves are replaced in October 2021. They are replaced with 20" carbon steel gate valves in preparation for the ten-year internal inspections of stripper reboilers (These valves isolate the reboilers from the stripper column). In Fall 2022, reboilers are still able to be isolated for yearly cleaning but fail to close in Spring 2023 for internal inspections.
[ul]
[li]SDS: 90% H2O, 6% ammonium sulfate, 2% acrylonitrile, 2% organics and cyanides.[/li]
[li]Operating Temp: 240F[/li]
[li]Operating Pressure: 13 psig[/li]
[li]pH should be controlled to 7.8[/li]
[li]Designed to be 10% vapor (90%) liquid[/li]
[li][/li]
[/ul]
Other items to note:
[ul]
[li]all piping is 304L,[/li]
[li]tubes on the reboilers are 304L,[/li]
[li]shell of reboiler is CS,[/li]
[li]50# steam is on shell side,[/li]
[li]Soda Ash and Sulfuric acid are used in this process stream as well.[/li]
[li]"Liquid in" valves for the reboilers were also replaced in 2021, very few or no signs of degradation[/li]
[li] Flashing is a constant or common occurrence[/li]
[/ul]
The piping shows no signs of similar degradation, the SS valves pulled in 2021 also did not show signs of degradation similar to the CS valves installed.
Really I am curious as to what may cause this type of damage, and so quickly. Looking into API 571 I see very similar damage compared to Amine Corrosion or CO2 Corrosion. Asking process engineering, it's not likely that these could cause damage as the scenario would be hard to develop. From what I see, it looks like mesa-type corrosion, tunneling I compare to ash bore beetles, and straight-lined damage I could only compare to damage seen in 600# steam services from cavitation.
Determining the root cause of this failure seems to have me on a roadblock so any guidance would be appreciated.
Mechanical Integrity Specialist (Year 1)
[ul]
[li]SDS: 90% H2O, 6% ammonium sulfate, 2% acrylonitrile, 2% organics and cyanides.[/li]
[li]Operating Temp: 240F[/li]
[li]Operating Pressure: 13 psig[/li]
[li]pH should be controlled to 7.8[/li]
[li]Designed to be 10% vapor (90%) liquid[/li]
[li][/li]
[/ul]
Other items to note:
[ul]
[li]all piping is 304L,[/li]
[li]tubes on the reboilers are 304L,[/li]
[li]shell of reboiler is CS,[/li]
[li]50# steam is on shell side,[/li]
[li]Soda Ash and Sulfuric acid are used in this process stream as well.[/li]
[li]"Liquid in" valves for the reboilers were also replaced in 2021, very few or no signs of degradation[/li]
[li] Flashing is a constant or common occurrence[/li]
[/ul]
The piping shows no signs of similar degradation, the SS valves pulled in 2021 also did not show signs of degradation similar to the CS valves installed.
Really I am curious as to what may cause this type of damage, and so quickly. Looking into API 571 I see very similar damage compared to Amine Corrosion or CO2 Corrosion. Asking process engineering, it's not likely that these could cause damage as the scenario would be hard to develop. From what I see, it looks like mesa-type corrosion, tunneling I compare to ash bore beetles, and straight-lined damage I could only compare to damage seen in 600# steam services from cavitation.
Determining the root cause of this failure seems to have me on a roadblock so any guidance would be appreciated.
Mechanical Integrity Specialist (Year 1)