An aluminium fitting would not normally be acceptable. The Jetstream 32 horsecollar was arguably a fitting, and was a solid bent bar of aluminium. It passed the test of the 2000 F burner on it with load. However, that was to Part 23 and was in the late 70s or early 80s, and I don't think you'd get away with it even to Part 23 these days, let alone Part 25. (It didn't melt because the burner flame is a limited size, and it was able to conduct the heat away to the cool(er) areas.)
You can get away with an aluminium sheet as a fire barrier IF it has adequate cooling air flowing over the back face. Aluminium has also been used as a fire barrier if coated with intumescent paint or similar. However, it might be problematic to get the authorities to accept such coatngs these days (you have to prove that the coating won't come off, etc.), and also some of the materials are toxic. NB: carbon/epoxy can be a weight and cost effective alternative to titanium for lightly loaded firewalls.
For fittings, fire zones usually use titanium and stainless steel. However, the ATP had some carbon/epoxy struts in the nacelle, and these were protected by stainless steel and insulation. So, you might get away with aluminium if it was adequately protected. Usually the added expense and testing of such things means you're better off with titanium, in spite of the astronomical raw material cost (I'm a bit out of date, but last time I checked 6-4 was above $60/lb).