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How to remove copper from carbon steel substrate? 1

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CdotS

Materials
Jan 24, 2002
79
What is the best solution (acid or otherwise) to remove copper deposits a mild steel without affecting the substrate underneath?
 
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An interesting problem because it is generally recognized that copper is much more corrosion resistant than iron.

One possibility might be to use a nitric acid solution sufficiently strong to passivate the iron but attack the copper.

Other possibilities:
hydrocyanic acid (ugh!)
hot isopropyl acid
metallic mercury (probably your best bet).
 
Copper is soluble in ammonia solutions and carbon steel is not. I would expect a 10- 15 % solution of ammonium hydroxide in water at about 70C to give reasonbly good copper removal efficiency. Let us know what you decide.
 
Ferric chloride is used to etch copper from circuit boards but I have no idea how it will affect the steel.
 
Ferric Chloride is nasty stuff. It will attack most metals including Cu and Fe at a large range of concentrations.

Tim
 
(Vijay Cor Eng)

Etch blast the surface with fine garnet you can remove the copper as well as polish the surface.
 
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