Watch out with the delay time for gaining strength. Also, the finishers need to be specially trained and possibly even use a mockup to test the finishing procedures, since high volume fly ash has different characteristics. Also be careful with curing as well as the color finish of the concrete. High volume slag can get a green color to it. The best place for high volume flyash is foundations and piles, since they don't need substantial strength gain early on. You need to be careful with slabs, because if the forms are pulled to early and there isn't enough strength slab cracking may occur.
A good person to talk to is Steve Ratchye of Thornton Tomasetti San Francisco. He's considered an expert when it comes to green concrete.
Bruce Kings book Making Better Concrete - Guidelines to Using Fly Ash for Higher Quality, Eco-Friendly Structures by Bruce King, P.E. is a good reference.
PCA's book on concrete design is good as well.
Just remember fly ash is not really green anyway...even though LEED says so...after all, if we elminated the high energy, high pollution, steel mills and concrete planst, we wouldn't have fly ash.