Methanol Storage, venting

[albuz]

I am installing a 10,000 gallon methanol tank into a biodiesel plant, has anyone done this that can give me an idea of venting requirements, also this tank will be a double wall certified tank, will i have to have leak detection in the space between the two tanks? This project is in FL.
Thank You,
T

 

[dcasto]

If you don't monitor the are between the double wall, then why have it?

Methanol absorbes water and O2 from the atmoshere and becomes corrosive. We always blanket our small methanol tanks with natural gas. On a larger tank I'd investigate N2 as a blanket with a way to recylce the N2/CH3OH vapors via a compressor/surge tank.

 

[albuz]

i plan on using a N2 generator for blanketing, and will be closed loop, is there a problem with venting extra vapors to atmosphere>

 

[MJCronin]

allbuzzed...

Some important points to consider about vent systems for bulk Methanol tanks:

- The LEL and UEL for methanol are not the same as gasoline tanks; ensure that you inerting system designer is experienced and aware of the differences.

See this link:

http://sra-e-2006.ijs.si/files/contributions/900/904 Hedlund FH Andersen HB-revCnp.ppt

This would be a useful report for the design of your installation, but I cannot find it anywhere on the net.....can anyone help..???


"METHANOL TANK FIRES". By:. Robert L. Smith, CFEI, CFII. Staff Safety Engineer. Environmental, Health and Safety
Department. Ashland, Inc.

My opinion only

MJC

 

[dcasto]

I would look at some level of VRU or at least a chiller system to recover methanol from the vent line.

 

[JLSeagull]

Although 10,000 gallons is a small tank, look at the API and NFPA storage tank requirements for guidance.

 

[Montemayor]

Albuz:

Go to Post #58 written Oct 11, 2006 at:

http://www.cheresources.com/invision/index...&#entry8874

and you will find the tools necessary to analyze and identify the venting requirements, blanketing, and type of relief needed by your tank.

You state you're installing secondary containment. Is this truly a "double" tank? I've done secondary containment with raised MeOH tanks inside a concrete containment area and this is less expensive and more flexible that a "Double" tank.

 

[finechem]

Methanol does not have a high vapor pressure and will therefore not present a significant loss in a nitrogen vapor space at amb temp. Best way to pad this tank is N2 regulator @ 4"w.c. and a conservation vent (weighted, or spring opposed, would recommend with vacuum breaker at 0 "w.c.) set to open at ~10"w.c.. Any cons. vent manufacturer will have formulas in their brochure for calculating inbreathing (N2 regulator sizing) and outbreathing (conservation vent sizing), usually based on API STD 2000. Also, MJCRONIN is absolutely right about inerting prior to 1st use - limiting oxygen conc is around 10%, therefore inert down to around 4% oxygen. One final note - conservation vent cannot be used as the emergency vent... Good luck.

 

[DeltaCascade]

Also see recomended practice of API-2000, ... Tank Venting Requirements